Cobalt-catalyzed carboxylation of propargyl acetates with carbon dioxide.

نویسندگان

  • Keisuke Nogi
  • Tetsuaki Fujihara
  • Jun Terao
  • Yasushi Tsuji
چکیده

The cobalt-catalyzed carboxylation of propargyl acetates with CO2 (1 atm) is described. The reaction proceeds at room temperature in the presence of Mn powder as a reducing reagent. Various propargyl acetates are converted to the corresponding carboxylic acids in good to high yields.

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عنوان ژورنال:
  • Chemical communications

دوره 50 86  شماره 

صفحات  -

تاریخ انتشار 2014